Electroluminescence of double-doped diamond thin films

A new electroluminescence device is fabricated by microwave plasma chemical vapour deposition system and electron beam vapour deposition system. It is comprised of highly doped silicon/diamond/boron/nitrogen-doped diamond/indium tin oxide thin films. Effects of process parameters on morphologies and structures of the thin films are detected and analysed by scanning electron microscopy, Raman spectrometer and x-ray photoelectron spectrometer. A direct-current (DC) power supply is used to drive the electroluminescence device. The blue light emission with a luminance of 1.2 cd·m^{- 2} is observed from this double-doped diamond thin film electroluminescence device at an applied voltage of 105 V.     

武昌地区街道尘埃磁学特征及其对环境污染的指示意义

对在武昌地区4个功能区域(青山、洪山、东湖风景区、东湖开发区)主要交通街道收集的尘埃样品进行详细的环境磁学测量,包括质量磁化率、频率磁化率、等温剩磁退磁系数以及典型样品的磁滞回线参数等。研究结果表明:尘埃样品中剩磁载体均以亚铁磁性矿物为主,样品中的磁性颗粒呈现低矫顽力的磁铁矿特征,软磁性的磁性矿物是样品剩余磁性的主要载体。尘埃样品χ、SIRM的区域分布特征受区域周围工业、车流量及道路状况等多种环境因素的影响,在4个功能区域中存在明显的磁性差异:青山工业区污染较重,东湖开发区、洪山、东湖风景区次之;硬剩磁(HIRM)的分布可能指示了道路交通来源的磁颗粒特征,东湖开发区和青山工业区由于行驶的货车和重型车辆较多,表现出硬剩磁量值较高。与其他城市(兰州、西安、南京、徐州等)相比,整个武昌地区街道尘埃样品的磁性含量仍较高,说明在城市环境方面还有待于进一步改善和保护。     

燕辽成矿带养马甸斑岩型钼矿成矿岩体的年代学、地球化学及成岩成矿环境

养马甸钼矿床位于燕辽钼(铜)成矿带东段的辽西地区。养马甸岩体由似斑状花岗岩、粗粒花岗岩和细粒花岗岩3个不同岩相组成,主要矿物为石英(30%～45%)、钾长石(35%～50%)、斜长石(15%～25%)和少量黑云母(3%～5%)。矿体主要赋存于养马甸岩体的细粒花岗岩中,少部分赋存在紧邻细粒花岗岩的粗粒花岗岩和似斑状花岗岩中。地球化学研究表明,养马甸岩体总体为富硅(w(SiO2)=69.26%～76.44%)、富碱(w(Na2O+K2O)=7.87%～8.81%),贫钙(w(CaO)=0.36%～1.33%)、镁(w(MgO)=0.17%～0.61%)和铁(w(FeOT)=1.47%～3.39%)的钾质(K2O/Na2O=1.05～1.31)—准铝质花岗岩(A/CNK=0.90～1.00)。该岩体总体富集大离子亲石元素(K、Rb、Th和LREE),高场强元素(Nb、Ta、Zr、Hf和HREE)亏损不明显,而中稀土相对亏损,在稀土元素配分图上呈左陡右缓的"V"型。岩石地球化学及矿物演化特征表明,养马甸岩体的不同岩相为同源岩浆经历不同程度分离结晶作用的产物,其母岩浆来源于高压麻粒岩相下地壳物质的部分熔融。成岩与成矿年代学研究表明,似斑状花岗岩的LA-ICP-MS锆石U-Pb年龄为(192.1±1.9)Ma,粗粒花岗岩的LA-ICP-MS锆石U-Pb年龄为(189.5±1.4)Ma,而细粒花岗岩的LA-ICP-MS锆石U-Pb年龄为(189.3±3.3)Ma。结合对已有资料的归纳和分析,认为养马甸斑岩钼矿形成于后造山背景下的陆内伸展环境,含矿岩体及斑岩型钼矿的形成可能与古亚洲洋残留地幔楔在早侏罗世的再活化有关。     

四川盆地雷口坡末期古岩溶特征及其对储层的影响——以龙岗地区雷口坡组四~3段为例

四川盆地龙岗地区中三叠统雷口坡组顶部雷四3段发育一套风化壳岩溶型白云岩储层。储层似层状成规模分布。古岩溶作用以表生裸露期风化壳岩溶作用为主,受古地质背景和风化壳岩性组合影响,古岩溶特征主要表现为:溶蚀时间较短,溶蚀作用较弱,充填作用及膏溶作用较强。在研究区内风化壳岩溶作用是影响储层发育的关键因素,它对储层既有建设性作用又有破坏性作用。     

川中雷口坡组四~3亚段地震相分析——应用波形分类技术研究沉积相的实例

在工区面积大、钻井少的情况下开展地震相研究,可以有效绘出沉积相展布图。对四川盆地中部雷口坡组四3亚段利用GS1和YS104两口井进行地震地质标定,建立了膏盐湖、白云岩坪及颗粒滩等几种不同沉积微相的地震响应模式。膏盐湖相表现为强振幅、高连续的地震响应,而颗粒滩及白云岩坪主要表现为中振幅、低连续的地震响应特征。在地质标定基础上,对全区利用波形分类技术开展地震相研究,恢复了古沉积环境,获得了颗粒滩相及白云岩坪的展布图,这些分布区是有利储层的发育区。龙岗—营山—南充—蓬溪一带处于颗粒滩、白云岩坪有利相带,且处于雷四3亚段地层剥蚀线附近,受岩溶改造强烈,储层较为发育,是川中地区的重要勘探对象。     

珠江口盆地流花油田新近系生物礁灰岩储层特征及成因分析

南海珠江口盆地东沙隆起流花油田新近系灰岩储层为典型的台地边缘生物礁储层。岩石类型包括皮壳状珊瑚藻黏结灰岩、缠绕状珊瑚藻-珊瑚骨架灰岩、泥晶有孔虫-珊瑚藻颗粒灰岩、亮晶有孔虫-珊瑚藻颗粒灰岩、含红藻石灰岩、泥晶珊瑚颗粒灰岩、生屑泥晶灰岩7类。孔缝类型丰富,包括泥晶基质溶孔、粒间溶孔、藻架溶孔、粒内溶孔、铸模孔、体腔孔、晶间微孔7类孔隙及溶蚀缝、珊瑚藻皮壳间隙缝、似缝合线溶蚀缝、构造缝4类裂缝。划分了孔洞-网状裂缝型、孔隙型、裂缝-孔洞型、致密裂缝型4种储集类型。皮壳状珊瑚藻灰岩属于孔洞-网状裂缝型储层,泥晶颗粒灰岩、含红藻石灰岩和红藻石灰岩属于孔隙型,珊瑚骨架灰岩属于裂缝-孔洞型,亮晶生屑灰岩和胶结作用较强的皮壳状藻灰岩属于致密裂缝型。沉积微相和成岩作用控制了不同储集类型的分布,生物礁形成过程中的多期暴露对沉积微相和储集空间有重要影响。沉积-成岩演化过程划分为早期成礁与早期暴露、晚期成礁与次级暴露、埋藏压实与泥岩再造水改造阶段、两期成藏与地下水溶蚀4个阶段。根据沉积-成岩演化分析,预测了研究区储集类型空间分布。     

矿物中4He同位素提取和含量测定研究

(U-Th)/He定年是一种有效的低温热年代学定年技术,现已被广泛应用于地质研究的各个领域,而矿物中4He同位素的有效提取和含量准确测定是该技术的关键。磷灰石和锆石是(U-Th)/He定年最常用的矿物,其4He提取条件及铀钍含量测定方法都较为成熟;而其他矿物(如磁铁矿、橄榄石、针铁矿、石榴子石等)的研究则相对较少。文章介绍了当前国内外(U-Th)/He研究中采用的4He同位素提取方法———真空炉加热法和激光加热法,激光加热法因具有低4He背景值和耗时短的优点而成为主要的提取方法。以磷灰石样品测试为例,介绍了成都地质矿产研究所建立的采用激光加热法和四极杆质谱提取4He同位素及其含量测量过程、含量计算和校正方法。指出未来(U-Th)/He测试技术除继续改进现有分析方法外,应加强对更多不同矿物的测试研究。     

Environmental geochemistry of an active Hg mine in Xunyang,Shaanxi Province,China

The Xunyang Hg mine (XMM) situated in Shaanxi Province is an active Hg mine in China. Gaseous elemental Hg (GEM) concentrations in ambient air were determined to evaluate its distribution pattern as a consequence of the active mining and retorting in the region. Total Hg (HgT) and methylmercury (MeHg) concentrations in riparian soil, sediment and rice grain samples (polished) as well as Hg speciation in surface water samples were measured to show local dispersion of Hg contamination. As expected, elevated concentrations of GEM were found, ranging from 7.4 to 410 ng m⁻³. High concentrations of HgT and MeHg were also obtained in riparian soils, ranged from 5.4 to 120 mg kg⁻¹ and 1.2 to 11 μg kg⁻¹, respectively. Concentrations of HgT and MeHg in sediment samples varied widely from 0.048 to 1600 mg kg⁻¹ and 1.0 to 39 μg kg⁻¹, respectively. Surface water samples showed elevated HgT concentrations, ranging from 6.2 to 23,500 ng L⁻¹, but low MeHg concentrations, ranging from 0.022 to 3.7 ng L⁻¹. Rice samples exhibited high concentrations of 50–200 μg kg⁻¹ in HgT and of 8.2–80 μg kg⁻¹ in MeHg. The spatial distribution patterns of Hg speciation in the local environmental compartments suggest that the XMM is the source of Hg contaminations in the study area.     

Effect of source water quality on arsenic (V) removal from drinking water by coagulation/microfiltration

The effect of the source water quality on As(V) removal by coagulation/microfiltration (C/MF) was investigated systematically using a jar test and a lab-scale test; the results of the lab-scale test coincide with those of the jar test. It showed that the increase of dissolved organic carbon (DOC), HPO₄ ²⁻ and HCO₃ ⁻ concentrations would moderately decrease As(V) removal, and the residual As(V) concentration in treated water is no more than 10 μg L⁻¹ when the concentration of DOC, HPO₄ ²⁻ and HCO₃ ⁻ in raw water is not beyond 9.22 mg L⁻¹, 1.6 mg L⁻¹ and 300 mg L⁻¹, respectively. Other co-ions, such as Cl⁻, NO₃ ⁻, F⁻, SO₄ ²⁻, and counter-ions including K⁺, Ca²⁺ and Mg²⁺, have little effect on As(V) removal. Both results of the jar test and the lab-scale test demonstrate that Fe³⁺ dose of 6 mg L⁻¹ is enough to eliminate the influence of HCO₃ ⁻ whose concentration changes from 350 mg L⁻¹ to 450 mg L⁻¹. In the lab-scale test, As(V) removal ranged from 92.8 to 98.2% at Fe³⁺ dose of 4 mg L⁻¹ and 5 mg L⁻¹ when As(V) concentration in raw water was about 100 μg L⁻¹. The results obtained in this study suggest that As(V) removal by C/MF process is sensitive to the quality of raw water, and a jar test needs to be done before C/MF process is used for arsenic removal from drinking water.     

The Tilt between Acretion Disk and Stellar Disk

The orientations of the accretion disk of active galactic nuclei (AGN) and the stellar disk of its host galaxy are both determined by the angular momentum of their forming gas, but on very different physical environments and spatial scales. Here we show the evidence that the orientation of the stellar disk is correlated with the accretion disk by comparing the inclinations of the stellar disks of a large sample of Type 2 AGNs selected from Sloan Digital Sky Survey (SDSS, York et al. 2000) to a control galaxy sample. Given that the Type 2 AGN fraction is in the range of 70–90 percent for low luminosity AGNs as a priori, we find that the mean tilt between the accretion disk and stellar disk is ~ 30 degrees (Shen et al. 2010).